|
|
a_1-oleoyl-2-acyl-[glycerolipid] + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> a_1-linoleoyl-2-acyl-[glycerolipid] + oxidized_ferredoxin + H2O
|
1.14.19.45
sn-1 oleoyl-lipid 12-desaturase
1.14.19.6
acyl-CoA (9+3)-desaturase
|
–
–
|
|
BRENDA:
BR51510
MetaCyc:
RXN-16386
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-CoA <=> 3-oxooctadecanoyl-[acyl-carrier_protein] + CO2 + CoA
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
BRENDA:
BS320882
|
|
|
|
palmitoyl-[acyl-carrier_protein] + H2O <=> fatty_acid + [acyl-carrier_protein] + H+
|
2.3.1.85
fatty-acid synthase system
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
–
|
|
BRENDA:
BS12701;
BS364432;
BS382837;
BS432386
KEGG:
R01706;
R08163;
R12329
MetaCyc:
RXN-17108;
RXN-7902;
RXN-9548;
RXN-9549
|
|
|
|
oleic_acid + CoA + ATP <=> oleoyl-CoA + AMP + diphosphate
|
1.13.12.7
firefly luciferase
6.2.1.12
4-coumarate---CoA ligase
6.2.1.3
long-chain-fatty-acid---CoA ligase
6.2.1.B3
|
–
–
–
–
|
|
BRENDA:
BS279
MetaCyc:
RXN-9644;
RXN0-7239
SABIO-RK:
10317
|
|
|
|
ATP + 8,11,14-eicosatrienoic_acid + CoA <=> AMP + diphosphate + 8,11,14-eicosatrienoic_acid
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
|
BRENDA:
BS443134
|
|
|
|
a_very-long-chain_trans-2,3-dehydroacyl-CoA + NADPH + H <=> behenoyl-CoA + NADP+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
|
BRENDA:
BS442250
|
|
|
|
a_1-linoleoyl-2-acyl-[glycerolipid] + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> a_gamma-linolenoyl-[glycerolipid] + H2O + oxidized_ferredoxin
|
1.14.19.46
sn-1 linoleoyl-lipid 6-desaturase
|
–
|
|
BRENDA:
BR51511;
BS432563
MetaCyc:
RXN-16385
|
|
|
|
oleoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + oleic_acid + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
–
–
|
|
BRENDA:
BR10674
KEGG:
R02814
MetaCyc:
3.1.2.14-RXN
|
|
|
|
8,11,14-eicosatrienoic_acid + ferricytochrome_b5 + O2 + H+ <=> arachidonic_acid + ferricytochrome_b5 + H2O
|
1.14.19.30
acyl-lipid (8-3)-desaturase
1.14.19.44
acyl-CoA (8-3)-desaturase
|
–
–
|
|
BRENDA:
BS432765
|
|
|
|
a_very-long-chain_(3R)-3-hydroxyacyl-CoA <=> very-long-chain_(2E)-2-enoyl-CoA + H2O
|
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
|
–
|
|
BRENDA:
BR50205
KEGG:
R10827
MetaCyc:
RXN-11750
|
|